Synthesis with Spectral Investigation of New Ligand Derived From Pyrimidine with Some Metal Complexes

Abstract

New ligand were synthesized by two steps in first steps were prepared chalcones compound from reacting of various
carbonyl compounds [3-amino acetophenone with salicyldehyde ,the second steps were closure of the ring by
reacting[chalcones compound[AS] with thiouria, then reaction mixture was reflux for [8h] to produce Pyrimidine
derivatives[AST] also prepared some complexes with Fe[II],Co[II], Ni[II],Cu[II] ,the ligand [AST]with its complexes
were characterized by [ [FT.IR, Uv-Vis, HNMR, Mass]–spectra ,elemental analysis, melting point, molar conductivity] .